Flow Injection Spectrophotometric Determination of Sulphide by Catalytic Reduction of Toluidine Blue
نویسندگان
چکیده مقاله:
Sulphide was determined spectrophotometrically at 628 nm and pH 6.7 based on its catalytic reduction of toluidine blue in the presence of Se(IV) using a flow injection system. After optimization of the measuring conditions the calibration curve was found linear up to 25 mg/mL and the detection limit was 0.3 mg/mL (30 mL injections). The relative standard deviation for the determination of 10 mg/mL sulphide was 1.2% (n=14). The injection rate was 30 h-1.
منابع مشابه
flow injection spectrophotometric determination of sulphide by catalytic reduction of toluidine blue
sulphide was determined spectrophotometrically at 628 nm and ph 6.7 based on its catalytic reduction of toluidine blue in the presence of se(iv) using a flow injection system. after optimization of the measuring conditions the calibration curve was found linear up to 25 mg/ml and the detection limit was 0.3 mg/ml (30 ml injections). the relative standard deviation for the determination of 10 mg...
متن کاملUltra-trace Determination of Palladium(II) by Spectrophotometric Flow Injection Analysis
Nowadays, palladium compounds due to their especial characteristics used in different industries, mainly in electrical power sources and chemical productions as a catalyst. Therefore, Pd concentration is increasing in our around that can be contaminant our environment due its toxic effects. In this work, a simple, selective and rapid flow injection method of analysis (FIA) has been developed fo...
متن کاملSpectrophotometric determination of catecholamines with metaperiodate by flow-injection analysis
A flow-injection spectrophotometric method for the determination of adrenaline and isoprenaline, based on the reaction with metaperiodate, is described. The calibration graphs are linear up to 2X 10e4 M. Flow injection allows the measurement of 120 samples per hour. The method was successfully applied to the determination of both catecholamines in pharmaceuticals.
متن کاملFlow injection spectrophotometric determination of bromoxynil herbicide by diazotization method.
A flow injection spectrophotometric method is proposed for the determination of bromoxynil herbicide. Bromoxynil was hydrolyzed with HCl and the resulting product, 3,5-dibromo-4-hydroxyaniline, was diazotized with nitrite and coupled with aniline. The absorbance of the azo dye was measured at 500 nm. The conditions were optimized for diazotization using FIA. The range of linearity was found to ...
متن کاملcatalytic spectrophotometric determination of vanadium (iv) based on the oxidation of alkali blue by potassium bromate
a simple, rapid and sensitive spectrophotometric method has been proposed for the determinationof vanadium (iv). the method is based on the catalytic effect of v (iv) on the oxidation of alkali blue bypotassium bromate at ph 4. the rate of decrease in the absorbance of alkali blue (at 572 nm) wasproportional to the concentration of v (iv) in the range of 100-6000 ng ml-1. the detection limit wa...
متن کاملSPECTROPHOTOMETRIC REACTION RATE METHOD FOR THE DETERMINATION OF NITRITE BY CATALYTIC ACTION ON NILE BLUE A BROMATE REACTION
A kinetic method developed for the determination of ultra-trace amounts of nitrite based on its catalytic effect on the reaction between potassium bromate and Nile blue A in strongly acidic media is reported. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of Nile blue A at 645 nm by the fixed-time method. The decrease in absorbance during the first...
متن کاملمنابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ذخیره در منابع من قبلا به منابع من ذحیره شده{@ msg_add @}
عنوان ژورنال
دوره 12 شماره 2
صفحات 69- 72
تاریخ انتشار 1993-12-01
با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.
کلمات کلیدی
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023